- Jiali Wang, Jiajun Lu, Xiuwen Zhao, Guichao Hu, Xiaobo Yuan, Junfeng Ren. Two-dimensional Janus AsXY (X = Se, Te; Y = Br, I) monolayers for photocatalytic water splitting. The European Physical Journal B, 2023; 96 (2) DOI: 10.1140/epjb/s10051-023-00486-2
Since hydrogen releases an abundance of energy when combusted, with only water as a by-product, it is now widely seen as an excellent alternative to fossil fuels. Splitting water molecules involves a ‘redox reaction,’ where electrons and holes participate in reduction and oxidation reactions. Since they are excellent semiconductors, 2D Janus materials are particularly well suited to catalysing this reaction. When an electron in a semiconductor’s insulating ‘valence band’ absorbs a photon, it is excited to the material’s ‘conduction band,’ leaving behind a positively charged hole. In turn, these materials as both source and acceptors of electrons — allowing redox reactions to occur more readily.
In their theoretical study, Ren’s team examined a group of four of these materials: with one surface composed of either selenium or tellurium, and the other from either bromine or iodine — with both sides sandwiching a middle layer of astatine. In these semiconductors, the energies of their valence and conduction bands were far enough apart to prevent electrons and holes from readily recombining: allowing them to combine electrons and holes to produce hydrogen and oxygen. With all four materials displaying excellent stability and light absorption, the researchers believe they could be incredibly promising candidates for catalysing the water splitting reaction. If these results can be reproduced in experiments, Ren’s team hope the four materials could become a key element of the global effort to eliminate our carbon emissions in the next few decades.
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2D Janus materials could harvest abundant hydrogen fuel
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